2015年8月9日星期日

High-silica zeolite ZSM-type zeolite

High-silica zeolite ZSM-type molecular sieves have a series, widely used for ZSM-5 zeolite , with the same structure of ZSM-8 and ZSM-11 zeolite; another group of ZSM-21, ZSM-35 and ZSM-38, etc. . molecular sieve beads zeolite is often called high-silica zeolite molecular sieve Si / AI ratio can be as high as 50 or more, ZSM-8 up to 100, this group also showed a molecular sieve hydrophobic properties.
Their structural unit and molecular sieve 4a similar, there are a pair of five-membered ring composed of non-cage-like cavity, only channel. ZSM-5 zeolite has two sets of cross-channel, one for straight and the other perpendicular to whom font, by ten yuan ring. Channel into an oval, its window diameter (0.55-0.60) nm. Belonging to the family of high-silica zeolite also all-silicon type Silicalite-1, ZSM-5 structure, like, Silicalite-2 with the same ZSM-11.

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