According
to the size and shape of the molecular sieves 3a adsorption of different choices,
that is, only those molecules smaller than the molecular sieve
adsorption pore.
For
small polar molecular sieve manufacturers and unsaturated molecules having selective
adsorption properties, the greater the polarity, the higher the degree
of unsaturation, the stronger its selective adsorption.
With a strong water absorption. Even higher at lower temperatures, a larger space velocity and water content, there is rather high water absorption capacity.
zeolite adsorbent zeolite is a silicate mineral water containing aluminum frame structure
2015年8月13日星期四
2015年8月9日星期日
High-silica zeolite ZSM-type zeolite
High-silica zeolite ZSM-type molecular sieves have a series, widely
used for ZSM-5 zeolite , with the same structure of ZSM-8 and ZSM-11
zeolite; another group of ZSM-21, ZSM-35 and ZSM-38, etc. . molecular sieve beads zeolite
is often called high-silica zeolite molecular sieve Si / AI ratio can
be as high as 50 or more, ZSM-8 up to 100, this group also showed a
molecular sieve hydrophobic properties.
Their structural unit and molecular sieve 4a similar, there are a pair of five-membered ring composed of non-cage-like cavity, only channel. ZSM-5 zeolite has two sets of cross-channel, one for straight and the other perpendicular to whom font, by ten yuan ring. Channel into an oval, its window diameter (0.55-0.60) nm. Belonging to the family of high-silica zeolite also all-silicon type Silicalite-1, ZSM-5 structure, like, Silicalite-2 with the same ZSM-11.
Their structural unit and molecular sieve 4a similar, there are a pair of five-membered ring composed of non-cage-like cavity, only channel. ZSM-5 zeolite has two sets of cross-channel, one for straight and the other perpendicular to whom font, by ten yuan ring. Channel into an oval, its window diameter (0.55-0.60) nm. Belonging to the family of high-silica zeolite also all-silicon type Silicalite-1, ZSM-5 structure, like, Silicalite-2 with the same ZSM-11.
2015年8月5日星期三
Zeolite transitional form of selective restriction
Some reaction, reactant molecules and their zeolite desiccant products are
not subject to restrictions window catalyst pore diffusion of knowledge
within the required holes or due to a larger cage cavity space to form
the corresponding transition states, or is restricted so that the
reaction can not be ; on the contrary, some of the reactions yo ah just a
small space of the transition state would not accept that kind of
restriction, which constitutes a selective type catalytic transition
state restrictions.
ZSM-5 zeolite used in this transition state selectivity of catalytic reactions, the biggest advantage is to prevent coking. Because ZSM-5 molecular sieve sylobead having a smaller than the other bore, is not conducive to Jiaosheng Cheng precursor polymerization reaction requires a large transition state formed. Thus has a longer life than other molecular sieves and amorphous catalyst.
ZSM-5 zeolite used in this transition state selectivity of catalytic reactions, the biggest advantage is to prevent coking. Because ZSM-5 molecular sieve sylobead having a smaller than the other bore, is not conducive to Jiaosheng Cheng precursor polymerization reaction requires a large transition state formed. Thus has a longer life than other molecular sieves and amorphous catalyst.
2015年8月1日星期六
Several patents of ZSM-5 Zeolite
Our patents on a wide range of molecular sieve, which on ZSM-5
zeolite patent projects is endless. Today, manufacturers of ZSM-5 5a molecular sieve Tech Shandong 齐鲁华 letter on to introduce several patents on ZSM-5 Zeolite.
Using the direct method of molecular sieve 5a catalyst developed a number of new patents:
(1) NKC-01: After the catalyst was replaced by a boron trifluoride catalyst in the synthesis of ethylene glycol ether production, yield increased by 20%, the main raw materials fell 21 percent, reduce the cost of 2,000 yuan per ton of product, and the elimination of boron trifluoride corrosion and contamination of the equipment on the environment. State Board of Education Science and Technology Progress Award.
(2) NKC-03 A: dehydration of ethanol to ethylene catalyst than conventional alumina catalyst low reaction temperature 100 ° C, 1-2 times higher airspeed, save energy, improve production efficiency. National Invention Award Sidengjiang.
(3) NKC-8912 catalyst ethylbenzene, ethanol synthesis for two ethylbenzene production, allows for two ethylbenzene selectivity of 95-98% dependent on imports for the production of long-xylene separation of adsorbent started a catalytic Synthesis of new technology, so that our "right B diphenyl," the production will achieve localization. This catalyst has been adopted by the National Natural Science Foundation, Department of Chemistry, chaired identification.
Using the direct method of molecular sieve 5a catalyst developed a number of new patents:
(1) NKC-01: After the catalyst was replaced by a boron trifluoride catalyst in the synthesis of ethylene glycol ether production, yield increased by 20%, the main raw materials fell 21 percent, reduce the cost of 2,000 yuan per ton of product, and the elimination of boron trifluoride corrosion and contamination of the equipment on the environment. State Board of Education Science and Technology Progress Award.
(2) NKC-03 A: dehydration of ethanol to ethylene catalyst than conventional alumina catalyst low reaction temperature 100 ° C, 1-2 times higher airspeed, save energy, improve production efficiency. National Invention Award Sidengjiang.
(3) NKC-8912 catalyst ethylbenzene, ethanol synthesis for two ethylbenzene production, allows for two ethylbenzene selectivity of 95-98% dependent on imports for the production of long-xylene separation of adsorbent started a catalytic Synthesis of new technology, so that our "right B diphenyl," the production will achieve localization. This catalyst has been adopted by the National Natural Science Foundation, Department of Chemistry, chaired identification.
2015年7月28日星期二
Japan CDS-1 successfully developed a new type of molecular sieve
Recently, Xiao Bian understand a message from the Japanese National
Institute of Advanced Industrial Science and Technology (AIST) synthesis
of a novel molecular sieve ethanol dehydration CDS-1 has been successfully developed.
It was prepared by a layered silicate, has a unique structure - by 13x molecular sieves stacking blocks. According to the institute, said the film chemistry lab, CDS-1 between its silicate layers has many pores. Research center will work processing CDS-1 into the film, mainly used for the separation agent catalyst. Typically, the use of a structure-directing agent (Structure-directing agent) complex can be formed by hydrothermal synthesis of nanosized pore size. These pores may be at about 420 ℃, using condensation polymerization method easily and economically be bonded together to form a silicate layer.
This made one molecular structure but retain the layered silicate framework is without precedent. Molecular sieves containing silicon, aluminum and oxygen atoms. When the silica-alumina composite containing a high proportion of silicon, called a high-silica zeolite. This kind of molecular sieve is hydrophobic and high temperature. AIST has a molecular sieve such intellectual property rights, the Department of silicon and oxygen by a silicate system. It is resistant to high temperature above 800 ℃ and chemical resistance. When immersed in a solution of an acid or a base, and still retains its original structure.
It was prepared by a layered silicate, has a unique structure - by 13x molecular sieves stacking blocks. According to the institute, said the film chemistry lab, CDS-1 between its silicate layers has many pores. Research center will work processing CDS-1 into the film, mainly used for the separation agent catalyst. Typically, the use of a structure-directing agent (Structure-directing agent) complex can be formed by hydrothermal synthesis of nanosized pore size. These pores may be at about 420 ℃, using condensation polymerization method easily and economically be bonded together to form a silicate layer.
This made one molecular structure but retain the layered silicate framework is without precedent. Molecular sieves containing silicon, aluminum and oxygen atoms. When the silica-alumina composite containing a high proportion of silicon, called a high-silica zeolite. This kind of molecular sieve is hydrophobic and high temperature. AIST has a molecular sieve such intellectual property rights, the Department of silicon and oxygen by a silicate system. It is resistant to high temperature above 800 ℃ and chemical resistance. When immersed in a solution of an acid or a base, and still retains its original structure.
2015年7月24日星期五
Molecular sieve Introduction
Molecular sieve is a cubic lattice aluminosilicate compound having.
Molecular sieve has a uniform porous structure, the diameter of its
pores of uniform size, these cavities can adsorb molecules smaller
diameter than the bore to the interior, and the polarity molecular sieve separation of
the molecules and the preferential adsorption of the unsaturated
molecules having a capacity, which can very different degree, a
different degree of saturation, and the boiling point of different
molecular size to separate different molecules, which has the effect of
"screening" of molecules, so called molecular sieves 13x molecular
sieves. Since the molecular sieves have a high adsorption capacity,
high thermal stability, etc. The other adsorbents that are not so widely
used to obtain the molecular sieve.
2015年7月20日星期一
oxygen therapy and oxygen care has an irreplaceable role and broad prospects for development
Appropriate oxygen, there microcirculation status, reducing the load of the respiratory system in order to maintain a certain oxygen partial pressure of alveolar gas necessary to reduce the amount 3a zeolite molecular sieves of load in order to maintain cardiac arterial partial pressure of oxygen required for a certain effect. Thus in clinical medicine, preventive medicine, first aid medicine, geriatrics, activated zeolite powder rehabilitation and health care and medicine,zeolite desiccant oxygen therapy and oxygen care has an irreplaceable role and broad prospects for development.
the oxygen demand for small-scale, but also the use of PSA oxygen, including PSA and VPSA oxygen molecular sieve adsorbent oxygen process, working principle is the use of highly efficient nitrogen-oxygen separation adsorbent nitrogen adsorption certain time desorption regeneration, cyclical operation, the purpose of the two towers or more adsorption towers in parallel, to achieve continuous production of oxygen.
the oxygen demand for small-scale, but also the use of PSA oxygen, including PSA and VPSA oxygen molecular sieve adsorbent oxygen process, working principle is the use of highly efficient nitrogen-oxygen separation adsorbent nitrogen adsorption certain time desorption regeneration, cyclical operation, the purpose of the two towers or more adsorption towers in parallel, to achieve continuous production of oxygen.
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